Product Data
SILICA ROCK and SAND
•  IDENTIFICATION OF THE SUBSTANCE /PREPARATION AND COMPANY / UNDERTAKING
Product Name: Silica Rock & Silica Sand
Product Use: Silica dioxide is known for its hardness. It is the principle component of most types of glass, used also in industries including metallurgical, chemical, Ferro-alloy, refractory, pottery, ceramics, paint, golf, leisure, construction and substances as concrete.
Other Names: Crystalline Silica - Quartz
Crystalline Silicon dioxide - Quartz
Silicic anhydride
Chert, Quartz
 
•  COMPOSITION / INFORMATION OF INGREDIENTS
Composition Information: Crystalline Silica (Silica dioxide)
Ingredients: Name CAS Proportion Hazard
Silicon Dioxide 7631-86-9 >99% Ref. Sec. 3
(OHS Act) 14808-60-7
Other impurities Balance to 100%
   
•  HAZARD IDENTIFICATION
Chronic Effect: Prolonged exposure to crystalline silica dust (<10µm) in significant quantities can lead to silicosis or in rare cases cancer.
Inhalation: Inhalation of airborne pollutants generated during handling, tipping & loading, pulverization, grinding or crushing may cause silicosis.
Ingestion: When silica is ingested orally it passes unchanged through the gastrointestinal tract, leaving no trace behind. Small pieces of Silica oxide are equally harmless, as long as they are not large enough to mechanically obstruct the GI tract, or jagged enough to lacerate it's lining. It is indigestible, with zero nutritional value and zero toxicity.
Skin: Due to the abrasiveness of quartz it may cause irritation to the skin.
Eye: Airborne particles may cause irritation to eyes. Symptoms may include redness, tearing, stinging and blurred vision.
   
•  FIRST AID MEASURES
Inhalation: PPE 3M FFP2 Type respirators as approved by the Government Mining Engineer. Take all relevant steps to eliminate / minimize the possible source creating airborne pollutants.
Ingestion: Where applicable wash mouth out with water.
Eye: Wearing of appropriate personal protective equipment safety goggles. If contact with the eye(s) occurs, wash with copious amounts of water holding eyelid(s) open. Take care not to rinse contaminated water into the non-affective eye. Seek medical attention.
First Aid Facilities: Eye wash and normal washroom facilities.
Advice to Doctor: Treat symptomatically.
   
•  FIRE FIGHTING MEASURES
Hazardous Combustion Products: Product not combustible.
Extinguishing Media: In case of fire in the surroundings: use water spray, dry chemicals, foam, or carbon dioxide whichever method is applicable to the combustible material.
Flash Point: Not applicable.
Ignition Temperature: Not applicable.
Flammable Limits: Not applicable.
   
•  ACCIDENTAL RELEASE MEASURES
Wear appropriate personal protective equipment and clothing to minimise exposure. Dispose of waste according to federal, Environmental Protection Authority and state regulations. If the spillage enters the waterways contact the Environmental Protection Authority, or your local Waste Management Authority.
   
•  HANDLING & STORAGE
Handling: Wearing of personal protective equipment to prevent breathing in of airborne pollutants is compulsory. When dealing with this product, repeated or prolonged skin exposure without protection should be prevented in order to lessen the possibility of skin disorders. It is essential that all who come into contact with this material maintain high standards of personal hygiene i.e. Washing hands prior to eating, drinking, smoking or using toilet facilities.
Storage: Where applicable dried silica sand should be stored in a shed preventing the product to become airborne by wind turbulence.
   
•  EXPOSURE CONTROLS / PERSONAL PROTECTION
National Exposure Standards: In terms of NOHSA regulation 9.2.(7) the concentration airborne pollutant to which a worker may be repeatedly exposed for normal 8-hour shift (or a 40-hour workweek) constitutes the Time-weighted Average (TWA) limit and is a concentration expressed in milligrams of pollutant per cubic metre of air that may not exceed 0.10mg/m³.
Respiratory Protection: Where airborne pollutants are generated and exposure standards are exceeded, select and use respirators in accordance with the Mine Health and safety Act SABS 0338, approved type: 3M FF2 type in accordance with SamQuarz Code of Practise.
Eye Protection: If possibility of eye contact exists safety glasses with side shields or goggles should be worn as per General Safety Regulations 2 Personal Safety Equipment & Facilities Occupational Health & safety Act No 85 of 1993.
Hand Protection: Impervious gloves recommended. Final choice of appropriate gloves will vary according to individuals occupation / tasks. Refer to SamQuarz Code of Practise i.e. Personal Protective Equipment.
Body Protection: Not normally required.
Engineering Controls: Ensure sufficient procedures and standards in place to keep airborne concentrations below exposure limits.
Biological Limit Values: No Biological limit available.
   
•  PHYSICAL AND CHEMICAL PROPERTIES
Appearance: White Greyish (solids / granules)
Odour: Odourless
Molecular Formula: SiO 2
Melting Point: ± 1650 ºC
Boiling Point: > 2 230 ºC
Solubility in Water: Not soluble.
Density: 2.65 g/cm³
PH value: Not available
Vapour Pressure: Not Applicable
Viscosity: Not Applicable
Flash Point: Non-flammable
Ignition Temperature: Non-flammable
Flammable Limits: Non-flammable
   
•  STABILITY AND REACTIVITY
Stability: Stable under normal conditions of storage and handling.
Hazardous Polymerisation: Will not occur.
Chemical Dangers: Reacts with strong oxidants causing fire and explosion hazard.
Hazardous Decomposition Products: Products is inert and not stored in confined spaces.
Conditions to Avoid: Generation of airborne pollutants.
   
•  TOXICOLOGICAL INFORMATION
Toxicology Information: Products not classified as toxic material.
   
•  ECOLOGICAL INFORMATION
Environmental Protection / Ecotoxicity: Silica and silicates occur very freely in nature and actually form a very high percentage of the earth's crust. As per Department of Minerals & Energy approved Environmental Management System.
Mobility: Not available.
Persistence / Degradability: Not available.
   
•  DISPOSAL CONSIDERATIONS
Dispose of according to relevant local, state and federal government Regulations and Approved Environmental Management System.
   
•  TRANSPORT INFORMATION
Not classified as Dangerous Goods by Road and Rail Department of Transport and Railway Safety Regulator.
Storage and Transport: Not classified as Dangerous Goods.
   
•  REGULATORY INFORMATION
Risk Phrase: R42 May cause sensitisation by inhalation
  R43 May cause sensitisation by skin contact
  R49 May cause cancer by inhalation
Safety Phrase: S22 Do not breathe dust
  S36 Wear suitable protective clothing
  S37 Wear suitable gloves
  S45 In case of accident or if you feel unwell, seek medical advice
  S53 Avoid exposure obtain special instructions before use
Poisons Schedule: Not scheduled
 
Vision and Mission
DISCLAIMER
The information and recommendations contained herein are based upon data believed to be accurate. However, no guarantee or warranty of any kind, express or implied is made with respect to the information contained herein.
SamQuarz (Pty) Ltd accepts no responsibility and disclaims all liability for any harmful effects, which may be caused by purchase, resale, use or reuse exposure to our silica sand . Customers-users of silica sand must comply with all applicable health and safety legislation and orders.
 
OTHER INFORMATION
Chief Safety Officer

Tel: 013 665 7233 or 013 665 7200

PLEASE NOTE: that although every care has been taken in compiling the above information, it is solely reliant upon data available to us at the date hereof. We believe the data to be correct, however for the reason just stated we are not in a position to warrant its accuracy. With that in mind and given that the full range of possibilities and conditions under which the information may be applied simply cannot be anticipated, YOU ARE CAUTIONED to make your determinations as to the veracity and the suitability of the information to the particular circumstances that apply, or may apply, to you from time to time. Consistent with that approach it is recommended that where you have a particular purpose that would necessitate a reliance on information of the nature herein you obtain your own independent expert advice particularly structured to the relevant purpose. If this material is printed, circulated, distributed or copied in any manner, it is not to be modified without prior written permission, and further, it is to include the wording of the above disclaimer.
SDS History
MSDS replace revision dated
16 July 1997
MSDS reviewed: 04/09/2007
MSDS reviewed: 22/09/2009
 
 
SamQuarz © 2010
Designed by Madcowontherun Designs